Yes, God's commandment to multiply supports a condom ban, because humans should have a lot of children. This is in the context of marriage of course, because according to the teachings of the Catholic church, sexual activity is only appropriate in the context of marriage. The Bible tells married couples to go forth and multiply in numbers.
The Catholic Church is against all methods of birth control. The church is against birth control pills as well as any type of sterilization. The Catholic church believes that sexual relations are for procreation only. Therefore, condoms would defeat the purpose of having intercourse. If you think otherwise, you might want to consider changing religions as your thought process is not in alignment with the Catholic Church.